Nope. I think you can in the app Buzz Player HD but you would need to read the info to verify. I recall reading somewhere that when in iTunes if you right click on the video file and get the info you can change it to TV show and also give it a name and that will supposedly create a folder with the TV show name and you can label the episode the name of the movie. For example name the TV show Action and then name the episode Die Hard. I have not tried this so I'm not sure if it works or not. Lame that apple won't let you create folders in the video app... maybe in iOS 5 you will be able to do this.