Ok, this is a problem that your internet provider can fix.
Normally, this problem occurs when using a pop and smtp account from your web site domain name.
Most of the hosting services block the smtp access to their outgoing server... othewhise some hackers could used it to spam without being traced.
So, you must provide your hosting company of the IP addresses to unlock.
I had the same problem when travelling in different internet cafés in Costa Rica.
